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Radical Polymerization of Styrene and Methyl Methacrylate with Ruthenium(II) Complexes

✍ Scribed by Arrowood, Benjamin N.; Lail, Marty; Gunnoe, T. Brent; Boyle, Paul D.


Book ID
127385538
Publisher
American Chemical Society
Year
2003
Tongue
English
Weight
110 KB
Volume
22
Category
Article
ISSN
0276-7333

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✍ Tsuyoshi Ando; Masami Kamigaito; Mitsuo Sawamoto πŸ“‚ Article πŸ“… 1997 πŸ› Elsevier Science 🌐 French βš– 676 KB

A series of initiators have been developed for living radical polymerization of methyl methacrylate (MMA) mediated by ruthenium(If) complexes [e.g., RuCI2(PPh3)3; Ph = C6H5]. These initiators include chloromethanes, ~-chloroesters, ct-chloroketones, and cc-bromoesters, among which CCI3COCH3, CHCI2CO