MALDI−TOF−MS Analysis of Ruthenium(II)-Mediated Living Radical Polymerizations of Methyl Methacrylate, Methyl Acrylate, and Styrene 1
✍ Scribed by Nonaka, Hirotaka; Ouchi, Makoto; Kamigaito, Masami; Sawamoto, Mitsuo
- Book ID
- 127099672
- Publisher
- American Chemical Society
- Year
- 2001
- Tongue
- English
- Weight
- 136 KB
- Volume
- 34
- Category
- Article
- ISSN
- 0024-9297
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A series of initiators have been developed for living radical polymerization of methyl methacrylate (MMA) mediated by ruthenium(If) complexes [e.g., RuCI2(PPh3)3; Ph = C6H5]. These initiators include chloromethanes, ~-chloroesters, ct-chloroketones, and cc-bromoesters, among which CCI3COCH3, CHCI2CO
## Abstract Organostibine‐mediated controlled/living radical polymerization of MMA was successfully achieved in room temperature ionic liquids (RTILs) [bmim]Tf~2~N and [bmim]PF~6~. The ln([M]~0~/[M]) increased linearly with increasing reaction time. The number‐average molecular weights of PMMA incr
## Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a “Full Text” option. The original article is trackable v