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Radical-Polar Crossover Domino Reaction Involving Alkynes: A Stereoselective Zinc Atom Radical Transfer

✍ Scribed by Alejandro Pérez-Luna; Candice Botuha; Franck Ferreira; Fabrice Chemla

Publisher
John Wiley and Sons
Year
2008
Tongue
English
Weight
257 KB
Volume
14
Category
Article
ISSN
0947-6539

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on the occasion of his 70th birthday We have recently shown that 3,4-disubstituted 3-methoxycarbonylpyrrolidines 1 can be constructed diastereoselectively by carbocyclization [1] of the zinc enolates derived from b-Nallyl aminoesters 2 (Scheme 1, path A) or by the domino 1,4-