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Domino 1,4-Addition/Carbocyclization Reaction through a Radical–Polar Crossover Reaction

✍ Scribed by Fabrice Denes; Fabrice Chemla; Jean F. Normant

Publisher
John Wiley and Sons
Year
2003
Tongue
English
Weight
129 KB
Volume
115
Category
Article
ISSN
0044-8249

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Domino 1,4-Addition/Carbocyclization Rea
Domino 1,4-Addition/Carbocyclization Reaction through a Radical–Polar Crossover Reaction
✍ Fabrice Denes; Fabrice Chemla; Jean F. Normant 📂 Article 📅 2003 🏛 John Wiley and Sons 🌐 English ⚖ 130 KB 👁 1 views

on the occasion of his 70th birthday We have recently shown that 3,4-disubstituted 3-methoxycarbonylpyrrolidines 1 can be constructed diastereoselectively by carbocyclization [1] of the zinc enolates derived from b-Nallyl aminoesters 2 (Scheme 1, path A) or by the domino 1,4-