✦ LIBER ✦

Radical pair mechanism of CIDEP: comparison of the cage and free-diffusion models

✍ Scribed by A.I. Shushin

Publisher: Elsevier Science
Year: 1990
Tongue: English
Weight: 711 KB
Volume: 170
Category: Article
ISSN: 0009-2614
DOI: 10.1016/0009-2614(90)87093-7

No coin nor oath required. For personal study only.

📜 SIMILAR VOLUMES

Radical pair mechanism of CIDEP generati

Radical pair mechanism of CIDEP generation. Contribution of the dipole—dipole interaction

✍ A.I. Shushin 📂 Article 📅 1991 🏛 Elsevier Science 🌐 English ⚖ 477 KB

The effect of the electron dipole-dipole interaction (DDI) in multiplet chemically induced dynamic electron polarization (CIDEP) generated in radical pair (RP) recombination is investigated. It is demonstrated within some models that DDI results in multiplet CIDEP like exchange interaction (EI ) but

A novel radical-triplet pair mechanism f

A novel radical-triplet pair mechanism for chemically induced electron polarization (CIDEP) of free radicals in solution

✍ C. Blättler; F. Jent; H. Paul 📂 Article 📅 1990 🏛 Elsevier Science 🌐 English ⚖ 459 KB

Transient alkyl radicals and triplet-state molecules are generated simultaneously in solution by laser flash irradiation, and chemically induced electron polarization (CIDEP) of the radicals is studied by time-resolved ESR spectroscopy. The presence of triplet-state molecules is found to induce emis

The electron spin polarized (CIDEP) spec

The electron spin polarized (CIDEP) spectra of isopropyl radicals. A test of radical pair mechanism theory

✍ K.A McLauchlan; D.G Stevens 📂 Article 📅 1985 🏛 Elsevier Science ⚖ 698 KB

The concentration dependence of the phas

The concentration dependence of the phase of radical-pair mechanism chemically induced dynamic electron polarization (CIDEP)

✍ F. Jent; H. Paul; K.A. McLauchlan; D.G. Stevens 📂 Article 📅 1987 🏛 Elsevier Science 🌐 English ⚖ 517 KB

In flash-photolysis experiments the phase of RPM polarization in the radicals commonly changes in time after the flash, the patterns observed at longer times being apparently inconsistent with observations on the same radical systems made using alternative experimental techniques. It is shown here t

The influence of ST−1 mixing in spectra

The influence of ST−1 mixing in spectra which exhibit electron spin polarization (CIDEP) from the radical pair mechanism

✍ C.D. Buckley; K.A. McLauchlan 📂 Article 📅 1987 🏛 Elsevier Science 🌐 English ⚖ 418 KB

The cage effect and ESR spectra of spin-

The cage effect and ESR spectra of spin-correlated radical pairs

✍ A.I. Shushin 📂 Article 📅 1989 🏛 Elsevier Science 🌐 English ⚖ 561 KB

Hore and McLauchlan that shortly after their formation geminate isopropylketyl radicals in isopropanol at law temperature ( ~200 K) exhibit ESR spectra with "antiphase" lineshape, i.e. lines with their low-field halves in emission and high-field halves in absorption. It is shown that a theory which