Radical-Mediated Carbonylation of Alkyl Iodides in Aqueous Media.
β Scribed by Masaharu Sugiura; Hiroyuki Hagio; Shu Kobayashi
- Publisher
- John Wiley and Sons
- Year
- 2004
- Weight
- 100 KB
- Volume
- 35
- Category
- Article
- ISSN
- 0931-7597
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## Abstract For Abstract see ChemInform Abstract in Full Text.
Free radical-mediated carboxylation is achieved by treatment of alkyl iodides with methyl oxalyl chloride and bis(tributyltin) in benzene at 350 nm to afford the corresponding acid chlorides as a major product along with a small amount of the methyl esters,
## Abstract For Abstract see ChemInform Abstract in Full Text.
## Abstract A new and effective BarbierβGrignard allylation of aldehydes or ketones has been carried out with nanoβaluminum powder in aqueous 0.1 molΒ·L^β1^ NH~4~Cl (aq.) under an atmosphere of nitrogen. Aromatic carbonyl compounds gave homoallylic alcohols in good yields. The effectiveness of react