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SnCl2-Mediated Carbonyl Allylation in Fully Aqueous Media.

✍ Scribed by Xiang-Hui Tan; Yong-Quan Hou; Chao Huang; Lei Liu; Qing-Xiang Guo

Publisher: John Wiley and Sons
Year: 2004
Weight: 46 KB
Volume: 35
Category: Article
ISSN: 0931-7597
DOI: 10.1002/chin.200443057

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✦ Synopsis

Abstract

For Abstract see ChemInform Abstract in Full Text.

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## Abstract A new and effective Barbier‐Grignard allylation of aldehydes or ketones has been carried out with nano‐aluminum powder in aqueous 0.1 mol·L^−1^ NH~4~Cl (aq.) under an atmosphere of nitrogen. Aromatic carbonyl compounds gave homoallylic alcohols in good yields. The effectiveness of react