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Free radical-mediated carboxylation by radical reaction of alkyl iodides with methyl oxalyl chloride

✍ Scribed by Sunggak Kim; Sang Yong Jon

Publisher: Elsevier Science
Year: 1998
Tongue: French
Weight: 192 KB
Volume: 39
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(98)01568-8

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✦ Synopsis

Free radical-mediated carboxylation is achieved by treatment of alkyl iodides with methyl oxalyl chloride and bis(tributyltin) in benzene at 350 nm to afford the corresponding acid chlorides as a major product along with a small amount of the methyl esters,

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