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Radical deamination reactions of relevance to aminoglycoside chemistry

✍ Scribed by Derek H.R. Barton; Gerhard Bringman; Geneviève Lamotte; Robyn S. Hay Motherwell; William B. Motherwell

Publisher
Elsevier Science
Year
1979
Tongue
French
Weight
171 KB
Volume
20
Category
Article
ISSN
0040-4039

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✦ Synopsis

Reduction of tert.-, sec.-and prim.-isonitriles with tributylstanne affords in good yieids,but at progressively higher temperatures, the corresponding hydrocarbons. Sec.-thiocyanates and selenocyanates are also smoothly reduced but via the isonitriles. All reactions are radical in character. alcohols'. We have recently described a new method for the radical deoxygenation of secondary Since the reaction proceeds via a radical chain mechanism it is especially useful in carbohydrate chemistry. The selective removal of an amino group by a conceptually similar

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