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On the isomerisation of the methoxy radical relevance to atmospheric chemistry and combustion

✍ Scribed by L. Batt; J.P. Burrows; G.N. Robinson

Publisher: Elsevier Science
Year: 1981
Tongue: English
Weight: 376 KB
Volume: 78
Category: Article
ISSN: 0009-2614
DOI: 10.1016/0009-2614(81)85238-4

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✦ Synopsis

Recent investigations of the chemistry of the hydroxymethyl and methovy radicals have susested that the unimolecalar isomerisation CHaO -CHzOH may be Important. The possible interfering role of this reaction m the reaction between the methovy radical and oxygen is investigated, and an estimate of its rate coefticient is determined from thermochemical considerations.

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