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Radical cyclisations of methylenecyclopropane derivatives

✍ Scribed by Christine Destabel; Jeremy D Kilburn; John Knight

Publisher: Elsevier Science
Year: 1993
Tongue: French
Weight: 232 KB
Volume: 34
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(00)93404-x

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✦ Synopsis

Radical cycliitions of various methylenecycbpopane derivatives have been stdied and it has been fotmd that methylenecyc~l pfopyl radicals undergo exclusive 5-cx0 cydhtion while methylenecycloppyl butyl mdicala give a mixtme of product9 resulting tium f&x0 and 7-efdo cyclisation. Attempted cyclisatioos of m*knecyclopropylptylmdicalskadston3hedpmductsonly.

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