𝔖 Bobbio Scriptorium
✦   LIBER   ✦

On the Regioselectivity of Imidoyl Radical Cyclisations

✍ Scribed by Daniele Nanni; Gianluca Calestani; Rino Leardini; Giuseppe Zanardi

Publisher
John Wiley and Sons
Year
2000
Tongue
English
Weight
336 KB
Volume
2000
Category
Article
ISSN
1434-193X

No coin nor oath required. For personal study only.

✦ Synopsis

The previously reported tandem cyclisation of N-aryl Ξ±-(2cyanophenyl)sulfanyl imidoyl radicals affords one quinoxaline derivative arising from exclusive 1,6-cyclisation of the final iminyl radical onto the N-aryl ring. When the imidoyl radicals are generated by addition of photolytically generated (2-cyanophenyl)sulfanyl radicals to isocyanides, the reaction also gives small amounts of a by-product that is formed by an analogous route and whose X-ray crystallo- [a]

πŸ“œ SIMILAR VOLUMES

On the Synthesis of N-Sulfonyl Substitut
On the Synthesis of N-Sulfonyl Substituted Imidoyl Azides
✍ Gerrit L'abbΓ©; Alex van Asch; FranΓ§oise Godts πŸ“‚ Article πŸ“… 2010 πŸ› Wiley (John Wiley & Sons) βš– 93 KB πŸ‘ 2 views

The high reactivity of imidoyl chlorides in nucleophilic displacement reactions is related to their facile isomerization into nitrilium ions.' with the azide ion to give imidoyl azides which may equilibrate with tetrazoles depending on the nature of the substituents, temperature and solvent used. Fo

ChemInform Abstract: Remarkable Dependen
ChemInform Abstract: Remarkable Dependence of the Regioselectivity of Free Radical Additions to 3-Cinnamoyloxazolidin-2-ones on the Stability of the Intermediate Adduct-Radical, Electrophilicity of the Adding Radicals and the Conditions for Their Generation.
✍ V. I. TARAROV; N. YU. KUZNETZOV; V. I. BAKHMUTOV; N. S. IKONNIKOV; Y. N. BUBNOV; πŸ“‚ Article πŸ“… 2010 πŸ› John Wiley and Sons βš– 43 KB πŸ‘ 2 views

Remarkable Dependence of the Regioselectivity of Free Radical Additions to 3-Cinnamoyloxazolidin-2-ones on the Stability of the Intermediate Adduct-Radical, Electrophilicity of the Adding Radicals and the Conditions for Their Generation. -The addition of nucleophilic and electrophilic radicals to t