Radical cations of cis- and trans-1,3-di- and 1,3,5-trimethylcyclohexanes. Matrix influence on two nearly degenerate SOMOs
โ Scribed by Lindgren, Mikael; Matsumoto, Michinobu; Shiotani, Masaru
- Book ID
- 120058664
- Publisher
- Royal Society of Chemistry
- Year
- 1992
- Tongue
- English
- Weight
- 821 KB
- Volume
- 9
- Category
- Article
- ISSN
- 1472-779X
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๐ SIMILAR VOLUMES
## Abstract From a 300 MHz spectral study of monoโto trisubstituted cyclohexanes, allowing a reโexamination of some of their ^1^H NMR spectral parameters, it is shown that it is possible to predict with reasonable accuracy the shifts (in CCl~4~) of the ring protons. A substantial feature in this is
Emission spectra of tram-and cis-1.3.5hexatricnc radical cations have been obtained in the gas phase by controlled clcctron impact excitation. Tbc band systems arc assigned to the x 2Bg + x 2Au and x 2Aa -, 2 lB8 transitions of the cations of the trans and cis isomers. rcspcctivcly. by rcfcrcncc to