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Radical allylation of α-silylacetic esters

✍ Scribed by Yannick Landais; Denis Planchenault

Book ID
103400604
Publisher
Elsevier Science
Year
1995
Tongue
French
Weight
896 KB
Volume
51
Category
Article
ISSN
0040-4020

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📜 SIMILAR VOLUMES

Intermolecular free radical reactions on
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✍ Mukund P. Sibi; Sithamalli V. Chandramouli 📂 Article 📅 1997 🏛 Elsevier Science 🌐 French ⚖ 214 KB

The first examples of intermoleeular free radical allylation reactions on solid support are reported. The allylation proceeds in good chemical efficiency with a variety of substrates as well as allylating agents. Control experiments indicate that the polymer matrix is inert to the reaction condition

Highly efficient and stereoselective rou
Highly efficient and stereoselective route to threo- and erythro-α-allylated α-fluoro-β-hydroxy esters via radical allylation reaction
✍ Takashi Ishihara; Kazuhide Mima; Tsutomu Konno; Hiroki Yamanaka 📂 Article 📅 2002 🏛 Elsevier Science 🌐 French ⚖ 92 KB

Treatment of a-bromo-a-fluoro-b-hydroxy esters with trimethylaluminum in dichloromethane, followed by reaction with allylic stannanes and a catalytic amount of triethylborane at -15°C, gave the corresponding threo-a-allylated a-fluoro-bhydroxy esters in a highly stereoselective manner. On the other