Intermolecular free radical reactions on solid support. Allylation of esters

✍ Scribed by Mukund P. Sibi; Sithamalli V. Chandramouli

• Book ID: 104258430
• Publisher: Elsevier Science
• Year: 1997
• Tongue: French
• Weight: 214 KB
• Volume: 38
• Category: Article
• ISSN: 0040-4039
• DOI: 10.1016/s0040-4039(97)10445-2

✦ Synopsis

The first examples of intermoleeular free radical allylation reactions on solid support are reported. The allylation proceeds in good chemical efficiency with a variety of substrates as well as allylating agents. Control experiments indicate that the polymer matrix is inert to the reaction conditions.