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Radical Addition Reaction of Brominated Active Methylene Compounds to Enol Ethers Using 2,2‘-Azobis(2,4- dimethyl-4-methoxyvaleronitrile) (V-70) as an Initiator

✍ Scribed by Kita, Yasuyuki; Sano, Atsunori; Yamaguchi, Takahiro; Oka, Masahisa; Gotanda, Kentoku; Matsugi, Masato

Book ID: 127040346
Publisher: American Chemical Society
Year: 1999
Tongue: English
Weight: 57 KB
Volume: 64
Category: Article
ISSN: 0022-3263
DOI: 10.1021/jo981900p

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ChemInform Abstract: Radical Addition Re

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Additions of malononitrile radicals to alkenes under mild conditions using 2,2′-azobis-(2,4-dimethyl-4-methoxyvaleronitrile) (V-70) as an initiator

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The attributes of 2,2'-azobis-(2,4-dimethyl-4-methoxyvaleronitrile) (V-70), which is an effective radical initiator at low temperature, in contrast to 2,2'-azobisisobutyronitrile (AIBN) are described.

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ChemInform Abstract: Additions of Malono

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ChemInform Abstract: Highly Stereoselect

ChemInform Abstract: Highly Stereoselective Synthesis of Carbocycles via a Radical Addition Reaction Using 2,2′-Azobis(2,4-dimethyl-4-methoxyvaleronitrile) [V-70L].

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