Racemic cis-bis(2,2′-bipyridyl)difluorovanadium(III) tetrafluoroborate
✍ Scribed by Kavitha, Savaridasson Jose ;Panchanatheswaran, Krishnaswamy ;Low, John N. ;Glidewell, Christopher
- Publisher
- International Union of Crystallography
- Year
- 2005
- Tongue
- English
- Weight
- 253 KB
- Volume
- 61
- Category
- Article
- ISSN
- 1600-5368
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📜 SIMILAR VOLUMES
In the crystal structure of the title compound, [RuCl 2 -(C 10 H 8 N 2 ) 2 ]ÁCH 2 Cl 2 , the complex consists of two bidentate 2,2 0 -bipyridyl N-atom donors and two chloride ions coordinated to an Ru II centre which lies on a crystallographic twofold rotation axis. Equivalent ligands are cis, each
Single-crystal X-ray study T = 298 K Mean '(C±C) = 0.007 A Ê Disorder in solvent or counterion R factor = 0.067 wR factor = 0.172 Data-to-parameter ratio = 12.4 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.
In the title compound, [V(C 9 H 11 )(C 5 H 7 O 2 ) 2 (C 4 H 8 O)], the V atom is octahedrally coordinated by two chelating acetylacetonate (acac) ligands in trans positions, one tetrahydrofuran (THF) ligand and one -bonded mesityl group.