rac-(Diisopropylamino)(1-indenyl)(isopropylamino)borane
✍ Scribed by Braunschweig, Holger ;Breitling, Frank Michael ;Seeler, Fabian
- Publisher
- International Union of Crystallography
- Year
- 2005
- Tongue
- English
- Weight
- 74 KB
- Volume
- 61
- Category
- Article
- ISSN
- 1600-5368
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The title complex, [Ni(C 13 H 16 N)Cl(C 18 H 15 P)]Á0.5C 4 H 10 O, consists of an Ni II center coordinated by a dimethylaminoethyl-substituted indenyl ligand, a triphenylphosphine ligand and a chloride ion. The asymmetric unit includes two very similar molecules that show only small conformational d
The molecular structure of (I), with displacement ellipsoids at the 30% probability level. H atoms have been omitted for clarity.
The title compound, C~26~H~29~N~3~O~8~, has two molecules in the asymmetric unit. Molecules are linked into chains by N—H...O hydrogen bonds, and C—H...O interactions are observed between chains.