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Chloro­[η5-1-(dimethyl­amino­eth­yl)inden­yl](triphenyl­phosphine)nickel(II) dieth­yl ether hemisolvate

✍ Scribed by Castonguay, Annie ;Beauchamp, André L. ;Vachon, Jason ;Zargarian, Davit

Publisher
International Union of Crystallography
Year
2005
Tongue
English
Weight
195 KB
Volume
61
Category
Article
ISSN
1600-5368

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✦ Synopsis

The title complex, [Ni(C 13 H 16 N)Cl(C 18 H 15 P)]Á0.5C 4 H 10 O, consists of an Ni II center coordinated by a dimethylaminoethyl-substituted indenyl ligand, a triphenylphosphine ligand and a chloride ion. The asymmetric unit includes two very similar molecules that show only small conformational differences in the indenyl side chain.

📜 SIMILAR VOLUMES

Chloro­[1-(di­methyl­amino­ethyl)­indeny
Chloro­[1-(di­methyl­amino­ethyl)­indenyl](tri­phenyl­phosphine)­nickel(II)
✍ Groux, Laurent F. ;Zargarian, Davit 📂 Article 📅 2001 🏛 International Union of Crystallography 🌐 English ⚖ 230 KB

Single-crystal X-ray study T = 223 K Mean '(C±C) = 0.005 A Ê Disorder in main residue R factor = 0.060 wR factor = 0.168 Data-to-parameter ratio = 14.1 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.