Some o-xylylene Co-quinodimethane) derivatives were isolated as stable crystalline materials. A strong through-bond interaction in tetracyanoethyZene addition product of tetraphenyZbensodicycZobutadiene ({I) is suggested.
Quest for a strong through bond interaction in [2.2]paracyclophane
✍ Scribed by Gleiter, Rolf ;Eckert-Maksić, Mirjana ;Schäfer, Wolfgang ;Truesdale, Elizabeth A.
- Publisher
- Wiley (John Wiley & Sons)
- Year
- 1982
- Tongue
- English
- Weight
- 147 KB
- Volume
- 115
- Category
- Article
- ISSN
- 0009-2940
No coin nor oath required. For personal study only.
📜 SIMILAR VOLUMES
## Abstract The PE. spectra of [2, 2]paracyclophane (**1**), 4‐amino[2, 2]paracyclophane (**2**) and 1, 1, 2, 2, 9, 9, 10, 10‐octafluoro[2, 2]paracyclophane (**3**) are presented. The bands corresponding to ejection of the photoelectron from the five highest occupied π‐orbitals have been assigned.
## Abstract The photoelectron spectra (PE.) of ten cyclophanes (**7** to **14, 16, 18**) have been assigned on the basis of a simple molecular orbital model proposed recently for the cyclophanes **2** (1,4) to **6**. It is shown that the agreement between calculated and observed band positions prov
## Abstract The photoelectron spectra of bicyclo[3.2.2]nonane and its five dehydrogenated analogues are reported. Analysis of the π‐bands reveals that the unsymmetrical diene 5 retains the ‘natural order’ of the π‐orbitals present in the lower homologues, i. e. the in‐phase below the out‐of‐phase c