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Observation of Through-Hydrogen-Bond 2hJHC′ in a Perdeuterated Protein

✍ Scribed by Florence Cordier; Marco Rogowski; Stephan Grzesiek; Ad Bax

Publisher
Elsevier Science
Year
1999
Tongue
English
Weight
58 KB
Volume
140
Category
Article
ISSN
1090-7807

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## Abstract We report here the observation of __O__H…N hydrogen‐bond ^1h^__J__~N, OH~ scalar coupling in a biologically active natural product. The intramolecular hydrogen bond between the threonine hydroxyl (Thr‐OH) group and the thiazolyl nitrogen at the second thiazole ring (Thz‐2) in nocathiac