By monitoring the relative concentrations of mercury To atoms using absorption photometry, absolute rate constants have been measured for the excimer-forming reaction Hg (%) + H g + NZ -+ Hgz\* + NZ and for the quenching of Hg (VO) atoms by ethane, propane, deuterated propanes, and nitrous oxide.
Quenching cross sections for Xe(3P2) metastable atoms with simple molecules
β Scribed by J.E. Velazco; D.W. Setser
- Publisher
- Elsevier Science
- Year
- 1974
- Tongue
- English
- Weight
- 416 KB
- Volume
- 25
- Category
- Article
- ISSN
- 0009-2614
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β¦ Synopsis
The cross section for quenching of Xe(3P,, 8.3 eV) metastabie atoms by thirteen simple molecules has been measured using the tlowing-afterglow technique. Except for Ha and N larger than for quenching of Ar(3Pa). For both Ar(3 2' the cross sections for quenching of Xe('Pa) are Pa) and Xe( Pa) the magnitude of the quenching cross section for tire majority of the molecules is dominated by Iong range forces. The technique used for generating Xe13P2) was based upon the addition of Xe to a flow of argon metastable atoms which results in the transfer of energy from a large fraction of Ar metastabfe atoms to ground state Xe atoms. yielding Xe(3Pa) atoms.
π SIMILAR VOLUMES
The rate constants for the deactivation of Ar 3Pz metastables by 26 different molecules were measured and the corresponding cross sections calculated. The measurements were done in a "flowing'. afterglow system; the Ar 3p\* being produced by a low power microwave discharge. The concentration of Ar '
Cross sections for the quenching of Nat3 'PI by N2 have been measured as a function of the initial relative kinetic energy of collision. The results indicate that the cross section smoothly changes by a factor of two over the energy range 0.08-0.35 eV.