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Quantum Chemical Characterization of Cycloaddition Reactions between the Hydroxyallyl Cation and Dienes of Varying Nucleophilicity †

✍ Scribed by Cramer, Christopher J.; Barrows, Susan E.


Book ID
120475357
Publisher
American Chemical Society
Year
1998
Tongue
English
Weight
287 KB
Volume
63
Category
Article
ISSN
0022-3263

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✍ C. J. CRAMER; S. E. BARROWS 📂 Article 📅 2010 🏛 John Wiley and Sons ⚖ 24 KB 👁 1 views

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Hydroxyallyl cation and lithium and sodium oxyallyl cations are predicted to react with 1,3-butadiene both in a stepwise fashion and via concerted [4 3] cycloaddition with so-called extended stereochemistry. With hydroxyallyl cation, the stepwise process is preferred and subsequent second bond closu