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ChemInform Abstract: Quantum Chemical Characterization of Cycloaddition Reactions Between the Hydroxyallyl Cation and Dienes of Varying Nucleophilicity.

✍ Scribed by C. J. CRAMER; S. E. BARROWS


Publisher
John Wiley and Sons
Year
2010
Weight
24 KB
Volume
29
Category
Article
ISSN
0931-7597

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✦ Synopsis


Abstract

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✍ Christopher J. Cramer; Susan E. Barrows πŸ“‚ Article πŸ“… 2000 πŸ› John Wiley and Sons 🌐 English βš– 191 KB πŸ‘ 1 views

Hydroxyallyl cation and lithium and sodium oxyallyl cations are predicted to react with 1,3-butadiene both in a stepwise fashion and via concerted [4 3] cycloaddition with so-called extended stereochemistry. With hydroxyallyl cation, the stepwise process is preferred and subsequent second bond closu