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Cycloaddition Chemistry of 1,3-Dienes on the Silicon(001) Surface: Competition between [4 + 2] and [2 + 2] Reactions

โœ Scribed by Hovis, Jennifer S.; Liu, Hongbing; Hamers, Robert J.


Book ID
127387035
Publisher
American Chemical Society
Year
1998
Tongue
English
Weight
179 KB
Volume
102
Category
Article
ISSN
0022-3654

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Kinetics of the [2+ + 4]-Cycloaddition R
โœ Herbert Mayr; Joachim Henninger ๐Ÿ“‚ Article ๐Ÿ“… 1998 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 287 KB ๐Ÿ‘ 1 views

The kinetics of the [2 + + 4] cycloadditions of 1,3-dithian-2-cycloaddition pathway by the correlation lg k = s (E + N). Though a concerted cycloaddition pathway is not excluded ylium ions (1) with 1,3-dienes was investigated photometrically in dichloromethane. The second-order rate by this finding,