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Quantitative treatment of micellar effects upon the nucleophilicity of halide ions

โœ Scribed by Al-Lohedan, Hamad; Bunton, Clifford A.; Moffatt, John R.

Book ID
127195929
Publisher
American Chemical Society
Year
1983
Tongue
English
Weight
473 KB
Volume
87
Category
Article
ISSN
0022-3654

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Micellar effects upon the reaction of co
Micellar effects upon the reaction of cobalt complexes with alkyl halides
โœ Rebecca J. Allen; Clifford A. Bunton ๐Ÿ“‚ Article ๐Ÿ“… 1976 ๐Ÿ› Elsevier Science โš– 612 KB

The reactions of the cobalosime Co (DH); and the related Co(DOH)DOpn" are strongly catalyzed by cationic micelles of cetyltrimethylammonium bromide (CTABr). The rate enhancements for the cobaloxime reaction and for that of Co (DOH)DOpn" (in parentheses) are: EtBr -1 (8.5); ,2-C, H, I Cl, 220 (200);