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A quantitative treatment of micellar effects in moderately concentrated hydroxide ion

โœ Scribed by Bunton, Clifford A.; Moffatt, John R.

Book ID
127057797
Publisher
American Chemical Society
Year
1992
Tongue
English
Weight
670 KB
Volume
8
Category
Article
ISSN
0743-7463

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โœ Clifford A. Bunton; Nicholas D. Gillitt; Anurag Kumar ๐Ÿ“‚ Article ๐Ÿ“… 1996 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 544 KB

## Second-order rate constants of reactions of HO-with phosphate, phosphinate and thiophosphinate esters, (PhO)2P0.0C6H4NO~~p, Ph,PO.OC,H,NO,-p, Ph,PO.SPh, Ph,PO.SC,H,NO,-p and Ph,PO.SEt, go through minima with decreasing water content of H,O-MeCN or H,O-t-BuOH. The rate decrease is due to stabili