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Quantitative FTIR studies of the Ru3(CO)12 cluster supported on hydrated alumina

✍ Scribed by S. Dobos; I. Böszörményl; V. Silberer; L. Guczi; J. Mink

Publisher: Elsevier Science
Year: 1985
Tongue: English
Weight: 241 KB
Volume: 96
Category: Article
ISSN: 0020-1693
DOI: 10.1016/s0020-1693(00)93722-8

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✦ Synopsis

Recently there has been growing interest in the interaction of carbonyl clusters with oxidic surfaces. Because of its simple structure and well-known chemical behaviour, Rua(CO)iZ has been studied by several authors [l-4].

Qualitative examination of the IR spectra suggests that, depending on the circumstances, Rua(C0)i2 adsorbed on hydrated A1203 decomposes into three structures, for which the band pairs at about 2140-2070, 2070-2000 and 2050-1970 cm-', respectively, are characteristic. The interpretations of these band pairs are rather different [l-4].

In the present investigation FTIR spectroscopy and data analysis have been carried out on the Rus(CO)iZ/A120s system, in order to prove or disprove the existence of the above three structures.

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