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Quantitative analysis of photoisomerization rates in trans-stilbene and 4-methyl-trans-stilbene

✍ Scribed by Jürgen Troe

Publisher
Elsevier Science
Year
1985
Tongue
English
Weight
666 KB
Volume
114
Category
Article
ISSN
0009-2614

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✦ Synopsis

Recent measurements

of isomerization rates of electronically excited trans-stilbene in supersonic beams and in thermal gases are analyzed in terms of the RRKM theory. It is shown that statistical unimolecular rate theory can quantitatively account for the experimental results. The absence of a major methyl-substitution effect is well reproduced. A comparison of isolated-molecule and liquid-phase isomerization rates indicates so far not understood solvent effects.

📜 SIMILAR VOLUMES

ChemInform Abstract: The Photoisomerizat
ChemInform Abstract: The Photoisomerization of cis- and trans-Stilbene in Ionic Liquids.
✍ Carlos Lee; Gleb Mamantov; Richard M. Pagni 📂 Article 📅 2010 🏛 John Wiley and Sons ⚖ 28 KB 👁 2 views

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