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Quadrupole coupling in ClO3

✍ Scribed by J.R. Byberg


Book ID
103014898
Publisher
Elsevier Science
Year
1973
Tongue
English
Weight
200 KB
Volume
23
Category
Article
ISSN
0009-2614

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✦ Synopsis


The quadrupole interaction has been measured by ESR spectroscopy for the paramagnetic centers in irradiated KC103 zmd NaC103 which have previously been associated with ClOa radicals. The observed cylindriul quadrupole coupling is e2qQ = 42 + 3 MHz. a value consistent with the field gradient obtained from a modified extended Hiickel czlculation for ClOa. The calculation also yields unpaired spin populations in fair agreement with experiment.


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