✦ LIBER ✦

Pyrolysis of alkyl nitrites (RONO)

✍ Scribed by L. Batt; R. T. Milne

Book ID: 102444970
Publisher: John Wiley and Sons
Year: 1974
Tongue: English
Weight: 162 KB
Volume: 6
Category: Article
ISSN: 0538-8066
DOI: 10.1002/kin.550060615

No coin nor oath required. For personal study only.

✦ Synopsis

I t has been established via AHj"(RON0) and AHj"(R6) that AH1,z0 = 41.5 f

(1)'

📜 SIMILAR VOLUMES

The gas-phase pyrolysis of alkyl nitrite

The gas-phase pyrolysis of alkyl nitrites. III. Isopropyl nitrite

✍ L. Batt; R. T. Milne 📂 Article 📅 1977 🏛 John Wiley and Sons 🌐 English ⚖ 652 KB

The rate of decomposition of isopropyl nitrite (IPN) has been studied in a static system over the temperature range of 130-160°C. For low concentrations of IPN (1-5 X lO+M), but with a high total pressure of CF4 (-0.9 atm) and small extents of reaction ( ~1 % ) ~ the first-order rates of acetaldehyd

The gas-phase pyrolysis of alkyl nitrite

The gas-phase pyrolysis of alkyl nitrites. IV. Ethyl nitrite

✍ L. Batt; R. T. Milne 📂 Article 📅 1977 🏛 John Wiley and Sons 🌐 English ⚖ 673 KB

The rate of decomposition of ethyl nitrite (EN) has been studied in a static system over the temperature range of 162-218°C. The main products are formaldehyde, acetaldehyde, ethanol, and nitrous oxide. For low concentrations of EX (10-5-10-4M), but with a high total pressure of CF, (-0.9 atm) and s

The gas-phase pyrolysis of alkyl nitrite

The gas-phase pyrolysis of alkyl nitrites. IV. Ethyl nitrite

✍ L. Batt; R. T. Milne; R. D. McCulloch 📂 Article 📅 1977 🏛 John Wiley and Sons 🌐 English ⚖ 928 KB

The rate of decomposition of methyl nitrite (MN) has been studied in the presence of isobutane-t-BuH-(167-20O0C) and NO (170-200°C). In the presence of t-3uH (-0.9 atm), for low concentrations of MN (-10-4M) and small extents of reaction (4-10%), the firstorder homogeneous rates of methanol (MeOH) f

Heats of formation of C1C4 alkyl nitrite

Heats of formation of C1C4 alkyl nitrites (RONO) and their RO-NO bond dissociation energies

✍ L. Batt; K. Christie; R. T. Milne; A. J. Summers 📂 Article 📅 1974 🏛 John Wiley and Sons 🌐 English ⚖ 353 KB

The heats of formation of Cs and C, alkyl nitrites (RONO) have been determined via their heats of combustion by bomb calorimetry, thereby providing a complete set of values of AH'/ for CI-C, alkyl nitrites. The experimental values are in excellent agreement with values derived from group additivity

The gas-phase pyrolysis of alkyl nitrite

The gas-phase pyrolysis of alkyl nitrites. II. s-butyl nitrite

✍ L. Batt; R. D. McCulloch 📂 Article 📅 1976 🏛 John Wiley and Sons 🌐 English ⚖ 925 KB

The rate of decomposition of s-butyl nitrite (SBN) has been studied in the absence (130-160°C) and presence (160-200°C) of NO. Under the former conditions, for low concentrabions of SBN (6 x 10-5 -lO-4M) and small extents of reaction (-l.5yc), the first-order homogeneoris rates of acetaldehyde (AcH)

The gas-phase pyrolysis of alkyl nitrite

The gas-phase pyrolysis of alkyl nitrites VI. t-Amyl nitrite

✍ L. Batt; T. S. A. Islam; G. N. Rattray 📂 Article 📅 1978 🏛 John Wiley and Sons 🌐 English ⚖ 514 KB

The rate of decomposition of tert-amyl nitrite (t-AmONO) has been studied in the absence (120"-155°C) and presence (16Oo-190"C) of nitric oxide. In the absence of nitric oxide for low concentrations of tert-amyl nitrite (-10-4M) and small extents of reaction (-l%), the first-order homogeneous rates