Pyridinium Hydrobromide Perbromide: A Versatile Catalyst for Aziridination of Olefins Using Chloramine-T
โ Scribed by Ali, Sayyed Iliyas; Nikalje, Milind D.; Sudalai, A.
- Book ID
- 118738558
- Publisher
- American Chemical Society
- Year
- 1999
- Tongue
- English
- Weight
- 45 KB
- Volume
- 1
- Category
- Article
- ISSN
- 1523-7060
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๐ SIMILAR VOLUMES
N-Bromoamides catalyze effectively the aziridination of electron-deficient as well as electron-rich olefins using chloramine-T (N-chloro-N-sodio-p-toluenesulfonamide) as a nitrogen source under ambient conditions to afford the corresponding aziridines in good to excellent yields.
Iron(III) corroles were found to be more selective catalysts than analogous porphyrins for the aziridination of olefins by PhI NTs, and, most important, the iron(IV) corrole 1 displays the unique ability of utilizing Chloramine-T as nitrogen atom source.