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Iron(IV) corroles are potent catalysts for aziridination of olefins by Chloramine-T

โœ Scribed by Liliya Simkhovich; Zeev Gross

Book ID
104231765
Publisher
Elsevier Science
Year
2001
Tongue
French
Weight
63 KB
Volume
42
Category
Article
ISSN
0040-4039

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โœฆ Synopsis

Iron(III) corroles were found to be more selective catalysts than analogous porphyrins for the aziridination of olefins by PhI NTs, and, most important, the iron(IV) corrole 1 displays the unique ability of utilizing Chloramine-T as nitrogen atom source.

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N-Bromoamides as versatile catalysts for
N-Bromoamides as versatile catalysts for aziridination of olefins using chloramine-T
โœ Vinay V. Thakur; A. Sudalai ๐Ÿ“‚ Article ๐Ÿ“… 2003 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 424 KB

N-Bromoamides catalyze effectively the aziridination of electron-deficient as well as electron-rich olefins using chloramine-T (N-chloro-N-sodio-p-toluenesulfonamide) as a nitrogen source under ambient conditions to afford the corresponding aziridines in good to excellent yields.