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N-Bromoamides as versatile catalysts for aziridination of olefins using chloramine-T

โœ Scribed by Vinay V. Thakur; A. Sudalai


Book ID
104252810
Publisher
Elsevier Science
Year
2003
Tongue
French
Weight
424 KB
Volume
44
Category
Article
ISSN
0040-4039

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โœฆ Synopsis


N-Bromoamides catalyze effectively the aziridination of electron-deficient as well as electron-rich olefins using chloramine-T (N-chloro-N-sodio-p-toluenesulfonamide) as a nitrogen source under ambient conditions to afford the corresponding aziridines in good to excellent yields.


๐Ÿ“œ SIMILAR VOLUMES


Iron(IV) corroles are potent catalysts f
โœ Liliya Simkhovich; Zeev Gross ๐Ÿ“‚ Article ๐Ÿ“… 2001 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 63 KB

Iron(III) corroles were found to be more selective catalysts than analogous porphyrins for the aziridination of olefins by PhI NTs, and, most important, the iron(IV) corrole 1 displays the unique ability of utilizing Chloramine-T as nitrogen atom source.