Pyridine complexes of iron(III) tetramesitylporphyrin: Detailed NMR studies
โ Scribed by C. Todd Watson; Ursula Simonis; F. Ann Walker
- Publisher
- Elsevier Science
- Year
- 1993
- Tongue
- English
- Weight
- 88 KB
- Volume
- 51
- Category
- Article
- ISSN
- 0162-0134
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This review describes the relationship between the NMR chemical shifts and electronic structures of oneelectron oxidized products of iron(III) porphyrins such as iron(III) porphyrin radical cations or iron(IV) porphyrins. In the case of the former complexes, the iron(III) ions are classified into fo
The 13C NMR characteristics of the polyaminocarboxylate ligands EDTA ~(H0,CCH2)2NCHzCHzN(CH,C0,H),I, DTPA [(H02CCH,)zNCH2CH,N(CHzCOzH)CH,CH2N(CHzN(CHzCOzH)z and NTA [N(CH,C0,H)3] and their Tl(II1) complexes are reported. The pH dependence of the 13C shifts of the ligands is helpful in understanding