Purine N-oxides—XL: The 3-acyloxypurine 8-substitution reaction: Scope: Syntheses of 8-substituted xanthines and guanines
✍ Scribed by N.J.M. Birdsall; U. Wölcke; T.-C. Lee; G.B. Brown
- Book ID
- 108372723
- Publisher
- Elsevier Science
- Year
- 1971
- Tongue
- French
- Weight
- 804 KB
- Volume
- 27
- Category
- Article
- ISSN
- 0040-4020
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In a recent publication (2) on the rearrangement of purine j-N-oxides to 8-hydroxypurines in acid anhydrides, a postulated intermediate was the 0-acyl derivative of the N-oxide. Such an intermediate, 3-acetoxyxanthine (II), [ctx5 267 mp (E 14,000)], has now been prepared by
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