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The scope and limitations of the Suzuki–Miyaura cross-coupling reactions of 6- and 8-substituted 1,2,3,4-tetrahydroisoquinoline-3-carboxylates

✍ Scribed by Jeffrey M McKenna; John Moliterni; Ying Qiao

Book ID: 104231193
Publisher: Elsevier Science
Year: 2001
Tongue: French
Weight: 94 KB
Volume: 42
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(01)01132-7

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✦ Synopsis

Aryl-1,2,3,4-tetrahydroisoqinoline-3-carboxylates have been prepared by Suzuki-Miyaura cross-coupling reactions of the triflates or corresponding boronate esters. We have shown for the first time that a one-pot arylation of a triflate via the boronate ester can be achieved using an aryl chloride.

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