A circular dichroism-based detection system presents several advantages in the HPLC analysis of chiral compounds because of the selective monitoring of optically active molecules. Its use allows reliable determination of enantiomeric excesses and elution order. To this end, the application of empiri
Pulse radiolysis with circular dichroism detection
โ Scribed by Donald B. O'Connor
- Publisher
- Elsevier Science
- Year
- 1994
- Tongue
- English
- Weight
- 629 KB
- Volume
- 44
- Category
- Article
- ISSN
- 0969-806X
No coin nor oath required. For personal study only.
๐ SIMILAR VOLUMES
Multidimensional fluorescence-detected circular dichroism (FDCD) is used to investigate the binding of bilirubin to four mammalian serum albumins. It is shown that the complexes formed with the albumins have distinctly different FDCD spectra. The effect of the pH-dependent transition from basic to a
Sugar osazones (1,2) and their acetates have circular dichroism spectra with multiple Cotton effects, showing three typical bands. Band I is located between 340 and 420 nm, with a negative Cotton effect, when the C-3 hydroxyl is to the e in the Fischerformula. Band II is located between 240 and 340