Pseudohalides of Boron Subphthalocyanine
โ Scribed by Paton, Andrew S.; Morse, Graham E.; Castelino, David; Bender, Timothy P.
- Book ID
- 118003541
- Publisher
- American Chemical Society
- Year
- 2012
- Tongue
- English
- Weight
- 658 KB
- Volume
- 77
- Category
- Article
- ISSN
- 0022-3263
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๐ SIMILAR VOLUMES
Metal-mediated cross-coupling of alkynes has been applied for the first time to C-C bond formation in Subphthalocyanines. Triiodosubphthaloeyanine 1 was reacted with the corresponding terminal alkyne in the presence of bis[triphenylphosphine]palladium (II) dichloride and copper (1) iodide to give th
The four compounds in the series from chloro[subphthalocyaninato]boron(III) to chloro[subnaphthalocyaninato]boron (III) where synthesized in a one-pot reaction. To obtain a more soluble set of compounds, the mixture was then reacted with the sodium salt of trihexylsilanol. This mixture was separated