Compounds in the series from boron subphthalocyanine to boron subnaphthalocyanine

✍ Scribed by Christopher D. Zyskowski; Vance O. Kennedy

• Publisher: John Wiley and Sons
• Year: 2000
• Tongue: English
• Weight: 79 KB
• Volume: 04
• Category: Article
• ISSN: 1088-4246
• DOI: 10.1002/1099-1409(200012)4:8<707::aid-jpp285>3.0.co;2-v

✦ Synopsis

The four compounds in the series from chloro[subphthalocyaninato]boron(III) to chloro[subnaphthalocyaninato]boron (III) where synthesized in a one-pot reaction. To obtain a more soluble set of compounds, the mixture was then reacted with the sodium salt of trihexylsilanol. This mixture was separated by chromatography to provide trihexylsiloxy[subphthalocyaninato]boron(III), trihexylsiloxy[ SubN ~1~ P ~2~]boron(III), trihexylsiloxy[ SubN ~2~ P ~1~]boron(III) and trihexylsiloxy[subnaphthalocyaninato]boron(III). These compounds were characterized by ^1^ H NMR, EI-MS and UV-vis. They show interesting spectral features in the visible region.