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Pseudoelement Compounds, X Synthesis and Crystal Structure of New Complexes of the Typetrans-[Pt(H)X(PPh3)2 with Cyanamide and Cyanomethanide Ligands

✍ Scribed by Jäger, Lothar ;Tretner, Carola ;Hartung, Helmut ;Biedermann, Mathias


Publisher
Wiley (John Wiley & Sons)
Year
1997
Tongue
English
Weight
599 KB
Volume
130
Category
Article
ISSN
0009-2940

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✍ Pawan K. Khanna; Christopher P. Morley; Michael B. Hursthouse; K. M. Abdul Malik 📂 Article 📅 1995 🏛 John Wiley and Sons 🌐 English ⚖ 431 KB

Treatment of tetrakis(tripheny1phosphine)platinum with elemental selenium (red or vitreous) in toluene solution under reflux yields an insoluble solid. This dissolves in dichloromethane with reaction, eventually to form a I : I mixture of [PtCl,(PPh,)J and the new compound [Pt(Se,CH,) (PPh,)J, which