Pseudocontact shifts of the PMR signal of acetone in the second coordination sphere of aquo-ions of the rare earth elements
โ Scribed by E. E. Zaev; L. M. Khalilov
- Publisher
- SP MAIK Nauka/Interperiodica
- Year
- 1980
- Tongue
- English
- Weight
- 488 KB
- Volume
- 21
- Category
- Article
- ISSN
- 0022-4766
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๐ SIMILAR VOLUMES
Raman spectra of glassy aqueous rare earth chlonde solutrons are re orted. A drastic change of frequency in the 2+totally symmetnc stretching viiration (ur) for the Ln(H2O)r ions (Ln rare earth ran) is observed between Sm and Cd and 1s mterpreted as endence for a change in the mner-sphere hydration
I11c lirsl-order spt~rc~xin~~lc csprcssions for the electronic matrix ckments in tllc r;rdhtionlcss relaxation theory of I;I~~-GI~III km> in zntitls are @en. The non-ndhtivc cfrwts of li\_gnd vibrations atd the forbiddcnncss of non-radiative Irrrnsitions in somr special CWJS arc dsscribcd.