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Evidence for the change of inner-sphere hydration number of rare earth ions in the middle of the series

Publisher
Elsevier Science
Year
1980
Tongue
English
Weight
267 KB
Volume
72
Category
Article
ISSN
0009-2614

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πŸ“œ SIMILAR VOLUMES

Raman spectroscopic evidence for a discr
Raman spectroscopic evidence for a discrete change in coordination number of rare earth aquo-ions in the middle of the series
✍ H. Kanno; J. Hiraishi πŸ“‚ Article πŸ“… 1980 πŸ› Elsevier Science 🌐 English βš– 328 KB

Raman spectra of glassy aqueous rare earth chlonde solutrons are re orted. A drastic change of frequency in the 2+totally symmetnc stretching viiration (ur) for the Ln(H2O)r ions (Ln rare earth ran) is observed between Sm and Cd and 1s mterpreted as endence for a change in the mner-sphere hydration

Complex equilibria in capillary zone ele
Complex equilibria in capillary zone electrophoresis and their use for the separation of rare earth metal ions
✍ C. Vogt; S. Conradi πŸ“‚ Article πŸ“… 1994 πŸ› Elsevier Science 🌐 English βš– 717 KB

The separation of lanthanides by capillary zone electrophoresis is carried out by addition of a complex forming agent to the separation buffer, thus generating charge and mobility differences between the species. The choice of a suitable ligand and especially the precalculation of the optimum ligand