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Raman spectroscopic evidence for a discrete change in coordination number of rare earth aquo-ions in the middle of the series

โœ Scribed by H. Kanno; J. Hiraishi


Publisher
Elsevier Science
Year
1980
Tongue
English
Weight
328 KB
Volume
75
Category
Article
ISSN
0009-2614

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โœฆ Synopsis


Raman spectra of glassy aqueous rare earth chlonde solutrons are re orted. A drastic change of frequency in the 2+totally symmetnc stretching viiration (ur) for the Ln(H2O)r ions (Ln rare earth ran) is observed between Sm and Cd and 1s mterpreted as endence for a change in the mner-sphere hydration number of rare earth ions rn the series.


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