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Protonation of some arenes in an aprotic medium

โœ Scribed by Buchanan, A. C.; Dworkin, A. S.; Brynestad, J.; Gilpatrick, L. O.; Poutsma, M. L.; Smith, G. Pedro

Book ID
126028841
Publisher
American Chemical Society
Year
1979
Tongue
English
Weight
272 KB
Volume
101
Category
Article
ISSN
0002-7863

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Cathodic reduction of ฮฑ-bromopropiopheno
Cathodic reduction of ฮฑ-bromopropiophenone in an aprotic medium
โœ F. Barba; M.D. Velasco; A. Guirado; I. Barba; A. Aldaz ๐Ÿ“‚ Article ๐Ÿ“… 1985 ๐Ÿ› Elsevier Science ๐ŸŒ English โš– 109 KB

The cathodic reduction in an aprotic medium of ~t-bromopropiophenone produces 1,4-diphenyl-2,3-dimethyl-l,4-butanedione. This product is transformed by dehydration in 2,5-diphenyl-3,4-dimethylfuran. The reduction process is rationalized via anionic intermediates.