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Electrochemical reduction of pyrylium salts in an aprotic medium

โœ Scribed by N. T. Berberova; G. N. Dorofeenko; O. Yu. Okhlobystin

Book ID
112325333
Publisher
Springer US
Year
1977
Tongue
English
Weight
278 KB
Volume
13
Category
Article
ISSN
0009-3122

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Cathodic reduction of ฮฑ-bromopropiopheno
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โœ F. Barba; M.D. Velasco; A. Guirado; I. Barba; A. Aldaz ๐Ÿ“‚ Article ๐Ÿ“… 1985 ๐Ÿ› Elsevier Science ๐ŸŒ English โš– 109 KB

The cathodic reduction in an aprotic medium of ~t-bromopropiophenone produces 1,4-diphenyl-2,3-dimethyl-l,4-butanedione. This product is transformed by dehydration in 2,5-diphenyl-3,4-dimethylfuran. The reduction process is rationalized via anionic intermediates.