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Protonated nitric acid. Structure and relative stability of isomeric H2NO3+ ions in the gas phase

โœ Scribed by Cacace, Fulvio; Attina, Marina; De Petris, Giulia; Speranza, Maurizio

Book ID
126200778
Publisher
American Chemical Society
Year
1990
Tongue
English
Weight
586 KB
Volume
112
Category
Article
ISSN
0002-7863

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Structure of ions [ZnNCR]+ and [Zn(NCR)2
Structure of ions [ZnNCR]+ and [Zn(NCR)2]+ (R = H, CH3) in the gas phase
โœ Sergiu P. Palii; Nikolai I. Raevskii; Dmitrii V. Zagorevskii; Konstantin M. Indr ๐Ÿ“‚ Article ๐Ÿ“… 1991 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 235 KB

## Abstract Structures of [ZnNCR]^+^ and [Zn(NCR)~2~]^+^ ions (R = H, Me), which are abundant in the mass spectra of many types of coordination compounds, were studied by the MNDO method. In all cases the most stable isomers correspond to the zinc ion coordinated with the nitrogen(s) of the nitrile