Rate constants for the reactions of OH radicals and Cl atoms with CH,CH,NO>, CH,CH,CH,NO,, CH3CH2CH2CHzN02, and CH,CH2CH2CH,CH2N02 have been determined at 295+3 K and a total pressure of approximately 1 atm. The OH rate data were obtained using both the absolute rate technique of pulse radiolysis co
Gas phase proton-transfer equilibria in binary mixtures of CH3OH, CH3NO2 and HCOOH and the relative proton affinities of CH3OH, CH3NO2 and HCOOH
β Scribed by C.G. Freeman; P.W. Harland; M.J. McEwan
- Publisher
- Elsevier Science
- Year
- 1978
- Weight
- 658 KB
- Volume
- 28
- Category
- Article
- ISSN
- 0020-7381
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π SIMILAR VOLUMES
Viscosities of a ternary mixture containing CH COOCH , CH OH, and CH CH CH OH at T s 298.15 K and atmospheric pressure have been measured over the whole range of mixture compositions. Viscosity deviations and excess molar Gibbs energy of activation of flow for the ternary system were calculated and
Densities r and speeds of sound u have been measured for {x1CH3(CH2)3OH + x2CH3(CH2)4CH3 + (1-x1-x2)CH3(CH2)3NH2}, and the corresponding mixtures CH2)3NH2}, at T = 298.15 K. Using these results, the isentropic compressibilities kS, the excess isentropic compressibilities k E S , and the speed of sou
## Abstract Rate constants for the gasβphase reactions of CH~3~OCH~2~CF~3~ (__k__~1~), CH~3~OCH~3~ (__k__~2~), CH~3~OCH~2~CH~3~ (__k__~3~), and CH~3~CH~2~OCH~2~CH~3~ (__k__~4~) with NO~3~ radicals were determined by means of a relative rate method at 298 K. NO~3~ radicals were prepared by thermal d