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Gas phase proton-transfer equilibria in binary mixtures of CH3OH, CH3NO2 and HCOOH and the relative proton affinities of CH3OH, CH3NO2 and HCOOH

✍ Scribed by C.G. Freeman; P.W. Harland; M.J. McEwan


Publisher
Elsevier Science
Year
1978
Weight
658 KB
Volume
28
Category
Article
ISSN
0020-7381

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## Abstract Rate constants for the gas‐phase reactions of CH~3~OCH~2~CF~3~ (__k__~1~), CH~3~OCH~3~ (__k__~2~), CH~3~OCH~2~CH~3~ (__k__~3~), and CH~3~CH~2~OCH~2~CH~3~ (__k__~4~) with NO~3~ radicals were determined by means of a relative rate method at 298 K. NO~3~ radicals were prepared by thermal d