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Proton transfer reactions from NH acid to proton sponges in acetonitrile. part 2

✍ Scribed by Bogumił Brzezinski; Grzegorz Schroeder; Arnold Jarczewski; Eugeniusz Grech; Joanna Nowicka-Scheibe; Lech Stefaniak; Jan Klimkiewicz

Publisher
Elsevier Science
Year
1996
Tongue
English
Weight
425 KB
Volume
377
Category
Article
ISSN
0022-2860

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✍ John R. Penton; Heinrich Zollinger 📂 Article 📅 1981 🏛 John Wiley and Sons 🌐 German ⚖ 607 KB

## Abstract The __N__‐diazo coupling of __p__‐chloroaniline with __p__‐chlorobenzenediazonium tetrafluoroborate in acetonitrile at 30° shows non‐linear base catalysis by water. The results are interpreted in terms of the __S__~__E__~2 mechanism with rate‐limiting proton loss at low base concentrati