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Kinetics and mechanism of proton transfer reactions from NH acid to 1,2-bis(dialkylaminomethyl)benzene in acetonitrile

✍ Scribed by Grzegorz Schroeder; Bogumił Brzezinski; Arnold Jarczewski; Eugeniusz Grech; Joanna Nowicka-Scheibe


Publisher
Elsevier Science
Year
1995
Tongue
English
Weight
347 KB
Volume
344
Category
Article
ISSN
0022-2860

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The reaction between tris(acetylacetonato)magnanese(III) and hexa(N,N-dimethylformamide)iron(III) perchlorate in acetonitrile proceeds in two stages. The first stage corresponds to the reaction of pentacoordinated Fe(DMF)Zt with Mn(acac),l, and the rate-determining step of the second stage consists